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Laser diodes are Light-Emitting Diodes with two "mirrors" on the surface of the diode to create a laser cavity.
When the diode is forward-biased, charges are injected into the active area of the junction. Electrons and holes recombine in the junction creating spontaneous emission of photons.
These photons can cause other electron-hole pairs to recombine by stimulated emission. When the current is high enough, the device lases.